xmas is getting close & i think i'll santa my machine an additional graphic card - i crave computing power

i've got an alienware aurora r4 - nice machine that comes with its caveat: there is very little room for customization since each bolt & plug is proprietary.
its running a geforce 680 & i'm looking for advice to find a suitable companion.
i will get (daz)Octane 2.0 when its out (soon !) & with all the obscure tech thingies my noobyness cannot fathom, i was wondering:
the 680 is kepler architecture: can i pair it with maxwell (700+ series)?
the 680 has 2Go vram: if i get a second card with more memory, am i still stuck with the 2Go or does octane 2.0 remedies that ?
i dont play the lottery so... no titan black zz plural alpha for me.
thanks in advance for your suggestion (and patience with my ignorance of things tech).