Hi!
I happen to have the same 3D model as you. It was given away on the cover disk of 3D World DVD 128.
Having access to the same model motivated me to try and give you a few friendly pointers.
Please note I created this image tonight while my wife and son slept...so, it could be better, but anyway its good enough for some tips.
I tried to stay pretty much true to how you had your car placed, though I did angle it a bit more so that you could see the engine inside. Which leads me to point out, that if a person was to try and make this car look "Real", it needs some extra complexity tossed into the engine compartment...some wires running around inside, a battery with warning labels etc...you get the idea.
For the lighting I used a HDR file I have....and then I set Octane to use pathtracing.
Set the materials for your car, glass etc as you desire.
Then using the interactivity of Octane, spin the HDR around till you get a lighting and reflection look that you like on the cars paint and glass.
Another area I like to tweak (mine in the example could be better) is the headlights. Don't forget to make the internal reflectors shine by making them like chrome. It really helps to make the car look more real, for the headlights are like the eyes of a person.
The background scene is from Daz3d...I placed the car into that environment to give it something to reflect in the paint.
I am looking forward to one day perhaps having Backplate support with a shadow catcher in Octane..such makes compositing awesome..and it really adds a realistic touch to your renders. Without having a realistic backplate you run the risk of making your scene look "fake" due to the quality of your background models. There are some that can probably post great tips on creating realistic backgrounds. I'm still trying to find that magic forumla.
As to the camera, I just slid the sliders till everything was in focus. I prefer it that way for scenes such as this...though your taste may vary depending on the look you want.
In my sample I could have let it cook longer, for the glass has that grainy look you get if you don't let it cook long enough. But, since its getting late and I need to run off to bed..it has to do for now.
I hope the image and tips help a bit.....people here are friendly and willing to help...so, I thought I'd try and contribute a little help as well.
Mike